| Oxygen capture by sulfur in nickel thiolates CA Grapperhaus, MY Darensbourg Accounts of chemical research 31 (8), 451-459, 1998 | 368 | 1998 |
| Mononuclear (nitrido) iron (V) and (oxo) iron (IV) complexes via photolysis of [(cyclam-acetato) FeIII (N3)]+ and ozonolysis of [(cyclam-acetato) FeIII (O3SCF3)]+ in water … CA Grapperhaus, B Mienert, E Bill, T Weyhermüller, K Wieghardt Inorganic Chemistry 39 (23), 5306-5317, 2000 | 361 | 2000 |
| Structural, Spectroscopic, and Computational Study of an Octahedral, Non-Heme {Fe−NO}6-8 Series: [Fe(NO)(cyclam-ac)]2+/+/0 RG Serres, CA Grapperhaus, E Bothe, E Bill, T Weyhermüller, F Neese, ... Journal of the American Chemical Society 126 (16), 5138-5153, 2004 | 208 | 2004 |
| Beyond metal-hydrides: non-transition-metal and metal-free ligand-centered electrocatalytic hydrogen evolution and hydrogen oxidation AZ Haddad, BD Garabato, PM Kozlowski, RM Buchanan, ... Journal of the American Chemical Society 138 (25), 7844-7847, 2016 | 121 | 2016 |
| Metal-assisted ligand-centered electrocatalytic hydrogen evolution upon reduction of a bis (thiosemicarbazonato) Cu (II) complex AZ Haddad, SP Cronin, MS Mashuta, RM Buchanan, CA Grapperhaus Inorganic chemistry 56 (18), 11254-11265, 2017 | 120 | 2017 |
| Methylation of Tethered Thiolates in [(bme-daco)Zn]2 and [(bme-daco)Cd]2 as a Model of Zinc Sulfur-Methylation Proteins CA Grapperhaus, T Tuntulani, JH Reibenspies, MY Darensbourg Inorganic chemistry 37 (16), 4052-4058, 1998 | 101 | 1998 |
| Synthesis and oxygenation of a nickel (II) and zinc (II) dithiolate: An experimental and theoretical comparison CA Grapperhaus, CS Mullins, PM Kozlowski, MS Mashuta Inorganic chemistry 43 (9), 2859-2866, 2004 | 98 | 2004 |
| Proposed ligand-centered electrocatalytic hydrogen evolution and hydrogen oxidation at a noninnocent mononuclear metal–thiolate AZ Haddad, D Kumar, K Ouch Sampson, AM Matzner, MS Mashuta, ... Journal of the American Chemical Society 137 (29), 9238-9241, 2015 | 78 | 2015 |
| Unique Reactivity of a Tetradentate N2S2 Complex of Nickel: Intermediates in the Production of Sulfur Oxygenates VE Kaasjager, E Bouwman, S Gorter, J Reedijk, CA Grapperhaus, ... Inorganic chemistry 41 (7), 1837-1844, 2002 | 77 | 2002 |
| Subtle Bite-Angle Influences on N2S2Ni Complexes JJ Smee, ML Miller, CA Grapperhaus, JH Reibenspies, MY Darensbourg Inorganic Chemistry 40 (14), 3601-3605, 2001 | 77 | 2001 |
| Ligand-assisted metal-centered electrocatalytic hydrogen evolution upon reduction of a bis (thiosemicarbazonato) Ni (II) complex R Jain, AA Mamun, RM Buchanan, PM Kozlowski, CA Grapperhaus Inorganic chemistry 57 (21), 13486-13493, 2018 | 69 | 2018 |
| Antifungal activity of thiosemicarbazones, bis (thiosemicarbazones), and their metal complexes K Bajaj, RM Buchanan, CA Grapperhaus Journal of Inorganic Biochemistry 225, 111620, 2021 | 67 | 2021 |
| First {Fe−NO}6 Complex with an N2S3Fe−NO Core as a Model of NO-Inactivated Iron-Containing Nitrile Hydratase. Are Thiolates and Thioethers Equivalent … CA Grapperhaus, AK Patra, MS Mashuta Inorganic chemistry 41 (5), 1039-1041, 2002 | 66 | 2002 |
| Template Effect for O2 Addition across cis-Sulfur Sites in Nickel Dithiolates CA Grapperhaus, MY Darensbourg, LW Sumner, DH Russell Journal of the American Chemical Society 118 (7), 1791-1792, 1996 | 62 | 1996 |
| Singlet oxygen and the production of sulfur oxygenates of nickel (II) and palladium (II) thiolates CA Grapperhaus, MJ Maguire, T Tuntulani, MY Darensbourg Inorganic chemistry 36 (9), 1860-1866, 1997 | 58 | 1997 |
| Metal-Stabilized Thiyl Radicals as Scaffolds for Reversible Alkene Addition via C–S Bond Formation/Cleavage K Ouch, MS Mashuta, CA Grapperhaus Inorganic Chemistry 50 (20), 9904-9914, 2011 | 52 | 2011 |
| Synthesis, characterization, and biological activity of hybrid thiosemicarbazone–alkylthiocarbamate metal complexes SA Andres, K Bajaj, NS Vishnosky, MA Peterson, MS Mashuta, ... Inorganic Chemistry 59 (7), 4924-4935, 2020 | 51 | 2020 |
| Density functional theory investigations of NiN2S2 reactivity as a function of nitrogen donor type and N–H···S hydrogen bonding inspired by nickel-containing … CS Mullins, CA Grapperhaus, PM Kozlowski JBIC Journal of Biological Inorganic Chemistry 11, 617-625, 2006 | 51 | 2006 |
| Synthesis and Characterization of N2S3X−Fe Models of Iron-Containing Nitrile Hydratase CA Grapperhaus, M Li, AK Patra, S Poturovic, PM Kozlowski, MZ Zgierski, ... Inorganic chemistry 42 (14), 4382-4388, 2003 | 51 | 2003 |
| Redox-regulated ethylene binding to a rhenium-thiolate complex CA Grapperhaus, K Ouch, MS Mashuta Journal of the American Chemical Society 131 (1), 64-65, 2009 | 48 | 2009 |
Robert M. BuchananUniversity of LouisvilleVerified email at louisville.edu
